60 引文 斯高帕斯(Scopus)

摘要

A mixture of hospital post-commercial polymer waste (LDPE/HDPE/PP/PS) was pyrolyzed over various catalysts using a fluidized-bed reactor operating isothermally at ambient pressure. The yield of volatile hydrocarbons with zeolitic catalysts (ZSM-5 > MOR > USY) were higher than with non-zeolitic catalysts (MCM-41 > ASA). MCM-41 with large mesopores and ASA with weaker acid sites resulted in a highly olefinic product mixture with a wide carbon number distribution, whereas USY yielded a saturate-rich product mixture with a wide carbon number distribution and substantial coke levels. The systematic experiments discussed in this paper show that the use of various catalysts improves the yield of hydrocarbon products and provide better selectivity in the product distributions. A novel developed model based on kinetic and mechanistic considerations which take into account chemical reactions and catalyst deactivation for the catalytic degradation of commingled polymer waste has been investigated. This model represents the benefits of product selectivity for the chemical composition such as alkanes, alkenes, aromatics and coke in relation to the performance and the particle size selection of the catalyst used as well as the effect of the fluidizing gas and reaction temperature.
原文英語
頁(從 - 到)2305-2316
頁數12
期刊Fuel
89
發行號9
DOIs
出版狀態已發佈 - 2010

ASJC Scopus subject areas

  • 燃料技術
  • 能源工程與電力技術
  • 化學工程 (全部)
  • 有機化學

指紋

深入研究「Thermochemical conversion of polymer wastes into hydrocarbon fuels over various fluidizing cracking catalysts」主題。共同形成了獨特的指紋。

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