Study of the effect of annealing process on the performance of P3HT/PCBM photovoltaic devices using scanning-probe microscopy

Yu Ching Huang, Yu Chia Liao, Shao Sian Li, Ming Chung Wu, Chun Wei Chen, Wei Fang Su

研究成果: 雜誌貢獻文章

99 引文 斯高帕斯(Scopus)

摘要

We have studied the effect of annealing process on the performance of photovoltaic devices based on the bulk heterojunction of poly(3-hexylthiophene) and [6,6]-phenyl-C61 butyric acid methyl ester (P3HT/PCBM). By means of atomic force microscopy (AFM) and scanning of near-field microscopy (SNOM), we can observe the morphology evolution of the annealed P3HT/PCBM composite films. We also studied the changes of optical properties by absorption spectroscopy and the changes of composition distribution of annealed composite films. The results indicate the P3HT in the composite film gradually becomes an ordered structure with annealing. The ordered P3HT facilitates the charge transport. However, the film exhibits a large-scale (1 μm) PCBM aggregation after annealing for an extended period of time. The disrupted bi-continous phase retards the charge transport. Thus, the device efficiency reaches the highest (2.308%) after annealing at 140 °C for 30 min but decreases to 0.810% after 60 min annealing.
原文英語
頁(從 - 到)888-892
頁數5
期刊Solar Energy Materials and Solar Cells
93
發行號6-7
DOIs
出版狀態已發佈 - 六月 1 2009
對外發佈Yes

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films

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