3 引文 斯高帕斯(Scopus)

摘要

Conventionally, electrochemical polymerization of polypyrrole (PPy) was generally performed in deionized (DI) water-based electrolyte. In this work, an innovative and facile strategy to substantially enhance the electroactive surface areas of electrochemically polymerized PPy is proposed by using plasmon-activated water (PAW)-based electrolyte. Compared to the DI water-based system, the prepared PPy with higher electron transfer rate and more-reversible redox performance was observed by using PAW-based system. In addition, a greater electroactive surface area of three-dimensional PPy was obtained with PAW-based electrolyte. These distinct properties of PPy electrodes prepared with PAW were responsible for their better performances in supercapacitors (with ca. 25.2% increased capacitance) and sensors (with ca. 50.0% increased sensitivity), compared to those prepared with DI water. These encouraging findings show the potential of PPy prepared with newly developed PAW for application to PPy-related devices to further enhance various performances.
原文英語
頁(從 - 到)252-260
期刊Journal of the Taiwan Institute of Chemical Engineers
82
DOIs
出版狀態已發佈 - 一月 2018

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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