One-dimensional metal string complexes

Shie Ming Peng, Chih Chieh Wang, Yih Lih Jang, Yu Hua Chen, Feng Yin Li, Chung Yuan Mou, Man Kit Leung

研究成果: 雜誌貢獻Conference article同行評審

187 引文 斯高帕斯(Scopus)

摘要

The metal string complexes with different metal ions and various lengths have been successfully synthesized and structurally characterized. The crystal and molecular structure of nonanickel complex [Ni99-(peptea)4Cl2] which is the longest metal string at this moment will be reported. Crystal data for [Ni99-(peptea)4Cl2](C2H4Cl2)10: Space group, monoclinic C 2/c, a = 27.0453(6), b = 42.6678(5), c = 37.4268(6) angstroms, β = 109.539(1)°, V = 40702(1) angstroms3, Z = 12, RF = 12% for the observed reflections (I>2σ(I)). The band structure calculation of infinite one-dimensional metal chains of NiII and CrII based on the structure of nonanickel complex will be presented. Finally, the metal string complexes [MnIIL4X2] will be chemisorbed on the Ag or Au surface and the potential application of these complexes as a molecular metal wire will be demonstrated.

原文英語
頁(從 - 到)80-83
頁數4
期刊Journal of Magnetism and Magnetic Materials
209
發行號1-3
DOIs
出版狀態已發佈 - 2月 2000
對外發佈
事件Proceedings of the 1999 International Symposium on Advanced Magnetic Technologies (ISAMT'99) - Taipei, Taiwan
持續時間: 5月 24 19995月 25 1999

ASJC Scopus subject areas

  • 電子、光磁材料
  • 凝聚態物理學

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