Mesoporous silica-supported V-substituted heteropoly acid for efficient selective conversion of glycerol to formic acid

Ding Jier Yuan, Jingling Yang, Amol M. Hengne, Yi Tzu Lin, Chung Yuan Mou, Kuo Wei Huang

研究成果: 雜誌貢獻文章同行評審

8 引文 斯高帕斯(Scopus)

摘要

V-substituted polymolybdenum phosphoric acid (PVxMo) supported on mesoporous silica was prepared and investigated as a catalyst for the oxidation of glycerol to formic acid in a batch operation. Different synthetic methods for PVxMo supported on mesoporous silica were compared. Detailed characterizations of the final products were carried out by N2 adsorption and desorption, XRD, HR-TEM, SEM, ICP-OES, XANES, NH3-TPD, and FTIR to identify the chemical properties and the porous structure of silica-supported PVxMo, as well as the strong interactions between PVxMo with the silica skeleton. These critical properties explain the bifunctionality of silica-supported PVxMo as a catalyst for the selective oxidation of glycerol to formic acid with standing stability.

原文英語
頁(從 - 到)1-8
頁數8
期刊Journal of Saudi Chemical Society
24
發行號1
DOIs
出版狀態已發佈 - 1月 2020
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)

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