Fabrication of self-healable magnetic nanocomposites via Diels-Alder click chemistry

Yi Huan Lee, Yan Nian Zhuang, Hsin Ta Wang, Ming Feng Wei, Wen Chi Ko, Wei Jen Chang, Tun Fun Way, Syang Peng Rwei

研究成果: 雜誌貢獻文章

摘要

In this study, we report a novel approach to fabricate an organic/inorganic magnetic hybrid system capable of self-healing, wherein a polycaprolactone-poly(furfuryl glycidyl ether) copolymer (PCLF) serving as the structure template was first synthesized, followed by the incorporation of iron oxide nanoparticles-decorated multiwalled carbon nanotubes (IONPs-MWCNTs) and 1,1'-(methylenedi-4,1-phenylene)bismaleimide (BMI) into the polymer matrix to form a covalently crosslinked hybrid network via a Diels-Alder (DA) reaction. For this system, the reactive combination of diene and dienophile from furan/maleimide, MWCNT/furan, and MWCNT/maleimide could facilely induce multiple DA reactions that imparted a versatile route to efficiently introduce IONPs-MWCNTs into the organic polymer hosts, resulting in a uniform distribution of IONPs-MWCNTs that led to a hybrid system with superparamagnetic properties. Beside the magnetic behavior, such material synergistically exhibited a superior ability for healing scratch defects via a retro-DA reaction. Therefore, this crosslinked PCLF/BMI/IONPs-MWCNTs hybrid system which exhibits multifunctional properties including superparamagnetic behavior and self-repairability can serve as an intelligent material for developing advanced electromagnetic applications.
原文英語
文章編號506
頁(從 - 到)506
期刊Applied Sciences (Switzerland)
9
發行號3
DOIs
出版狀態已發佈 - 二月 1 2019

指紋

Multiwalled carbon nanotubes (MWCN)
Iron oxides
iron oxides
Diels-Alder reactions
Nanocomposites
nanocomposites
bismaleimide
Hybrid systems
carbon nanotubes
chemistry
Nanoparticles
Fabrication
nanoparticles
fabrication
furans
healing
Polycaprolactone
smart materials
Intelligent materials
Organic polymers

ASJC Scopus subject areas

  • Materials Science(all)
  • Instrumentation
  • Engineering(all)
  • Process Chemistry and Technology
  • Computer Science Applications
  • Fluid Flow and Transfer Processes

引用此文

Lee, Y. H., Zhuang, Y. N., Wang, H. T., Wei, M. F., Ko, W. C., Chang, W. J., ... Rwei, S. P. (2019). Fabrication of self-healable magnetic nanocomposites via Diels-Alder click chemistry. Applied Sciences (Switzerland), 9(3), 506. [506]. https://doi.org/10.3390/app9030506

Fabrication of self-healable magnetic nanocomposites via Diels-Alder click chemistry. / Lee, Yi Huan; Zhuang, Yan Nian; Wang, Hsin Ta; Wei, Ming Feng; Ko, Wen Chi; Chang, Wei Jen; Way, Tun Fun; Rwei, Syang Peng.

於: Applied Sciences (Switzerland), 卷 9, 編號 3, 506, 01.02.2019, p. 506.

研究成果: 雜誌貢獻文章

Lee, YH, Zhuang, YN, Wang, HT, Wei, MF, Ko, WC, Chang, WJ, Way, TF & Rwei, SP 2019, 'Fabrication of self-healable magnetic nanocomposites via Diels-Alder click chemistry', Applied Sciences (Switzerland), 卷 9, 編號 3, 506, 頁 506. https://doi.org/10.3390/app9030506
Lee, Yi Huan ; Zhuang, Yan Nian ; Wang, Hsin Ta ; Wei, Ming Feng ; Ko, Wen Chi ; Chang, Wei Jen ; Way, Tun Fun ; Rwei, Syang Peng. / Fabrication of self-healable magnetic nanocomposites via Diels-Alder click chemistry. 於: Applied Sciences (Switzerland). 2019 ; 卷 9, 編號 3. 頁 506.
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