Energy transfer induced improvement of luminescent efficiency and thermal stability in phosphate phosphor

Yun Zhao, Chun Che Lin, Yi Wei, Ting Shan Chan, Guogang Li

研究成果: 雜誌貢獻文章

8 引文 (Scopus)

摘要

Ce3+ and Eu2+/Tb3+/Mn2+ ions codoped Ca6BaP4O17 (CBPO) phosphors have been prepared via a high-temperature solid state reaction. The structural refinement indicates that the as-prepared phosphors crystallize in monoclinic phase (C2/m) and there are two Ca sites and one Ba site in host lattice. The doping ions are determined to occupy Ca sites and the emission of Ce3+ and Eu2+ ions at different Ca sites were identified and discussed. Since bright blue and yellow emissions were observed from Ce3+ and Eu2+ ions monodoped CBPO under n-UV excitation, respectively. They were codoped into the CBPO for designing energy transfer from Ce3+ to Eu2+ to improve the luminescence efficiency of Eu2+. In addition, Tb3+ ions were added into the CBPO:Ce3+ system for realizing highly efficient green emission. The energy transfer mechanisms from Ce3+ to Eu2+/Tb3+ ions were discussed. Interestingly, the incorporation of Mn2+ ions into the CBPO:Ce3+ system enhanced the blue emission of Ce3+ ions due to the modification of crystal lattice. Finally, the thermal stability of CBPO:Ce3+, Eu2+/Tb3+/Mn2+ phosphors were investigated systematically and corresponding mechanisms were proposed. Based on these results, the asprepared CBPO:Ce3+, Eu2+/Tb3+/Mn2+ phosphors can act as potential blue, yellow, green, and emission-tunable phosphors for n-UV based white LEDs.
原文英語
頁(從 - 到)4316-4330
頁數15
期刊Optics Express
24
發行號4
DOIs
出版狀態已發佈 - 二月 22 2016
對外發佈Yes

指紋

phosphors
phosphates
thermal stability
energy transfer
ions
crystal lattices
light emitting diodes
luminescence
solid state
excitation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

引用此文

Energy transfer induced improvement of luminescent efficiency and thermal stability in phosphate phosphor. / Zhao, Yun; Lin, Chun Che; Wei, Yi; Chan, Ting Shan; Li, Guogang.

於: Optics Express, 卷 24, 編號 4, 22.02.2016, p. 4316-4330.

研究成果: 雜誌貢獻文章

Zhao, Yun ; Lin, Chun Che ; Wei, Yi ; Chan, Ting Shan ; Li, Guogang. / Energy transfer induced improvement of luminescent efficiency and thermal stability in phosphate phosphor. 於: Optics Express. 2016 ; 卷 24, 編號 4. 頁 4316-4330.
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abstract = "Ce3+ and Eu2+/Tb3+/Mn2+ ions codoped Ca6BaP4O17 (CBPO) phosphors have been prepared via a high-temperature solid state reaction. The structural refinement indicates that the as-prepared phosphors crystallize in monoclinic phase (C2/m) and there are two Ca sites and one Ba site in host lattice. The doping ions are determined to occupy Ca sites and the emission of Ce3+ and Eu2+ ions at different Ca sites were identified and discussed. Since bright blue and yellow emissions were observed from Ce3+ and Eu2+ ions monodoped CBPO under n-UV excitation, respectively. They were codoped into the CBPO for designing energy transfer from Ce3+ to Eu2+ to improve the luminescence efficiency of Eu2+. In addition, Tb3+ ions were added into the CBPO:Ce3+ system for realizing highly efficient green emission. The energy transfer mechanisms from Ce3+ to Eu2+/Tb3+ ions were discussed. Interestingly, the incorporation of Mn2+ ions into the CBPO:Ce3+ system enhanced the blue emission of Ce3+ ions due to the modification of crystal lattice. Finally, the thermal stability of CBPO:Ce3+, Eu2+/Tb3+/Mn2+ phosphors were investigated systematically and corresponding mechanisms were proposed. Based on these results, the asprepared CBPO:Ce3+, Eu2+/Tb3+/Mn2+ phosphors can act as potential blue, yellow, green, and emission-tunable phosphors for n-UV based white LEDs.",
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