Effect of TiO2 nanoparticles on the improved surface-enhanced raman scattering of polypyrrole deposited on roughened gold substrates

Yu Chuan Liu, Ping I. Lin, Yit Tsong Chen, Ming Der Ger, Kuo Lung Lan, Chih Lung Lin

研究成果: 雜誌貢獻文章

34 引文 (Scopus)

摘要

We report here the first electrochemical oxidation-reduction cycle procedure to roughen gold substrates in 0.1 N HCl aqueous solution containing 1 mM rutile TiO2 nanoparticles under the irradiation of UV light. It is encouraging to find that the oxidized peak in the anodic scan, which is responsible for the surface-enhanced Raman scattering, increases significantly due to the effect of adding TiO2 under an electric field and UV irradiation. Moreover, the SERS spectrum of polypyrrole electrodeposited on the corresponding roughened gold substrate exhibits a 5-fold higher intensity compared to that without the contribution of TiO2 nanoparticles.

原文英語
頁(從 - 到)14897-14900
頁數4
期刊Journal of Physical Chemistry B
108
發行號39
DOIs
出版狀態已發佈 - 九月 30 2004
對外發佈Yes

指紋

polypyrroles
Polypyrroles
Gold
Raman scattering
Irradiation
Raman spectra
gold
Nanoparticles
nanoparticles
irradiation
electrochemical oxidation
Electrochemical oxidation
Substrates
Ultraviolet radiation
rutile
Electric fields
aqueous solutions
cycles
electric fields
polypyrrole

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

引用此文

Effect of TiO2 nanoparticles on the improved surface-enhanced raman scattering of polypyrrole deposited on roughened gold substrates. / Liu, Yu Chuan; Lin, Ping I.; Chen, Yit Tsong; Ger, Ming Der; Lan, Kuo Lung; Lin, Chih Lung.

於: Journal of Physical Chemistry B, 卷 108, 編號 39, 30.09.2004, p. 14897-14900.

研究成果: 雜誌貢獻文章

Liu, Yu Chuan ; Lin, Ping I. ; Chen, Yit Tsong ; Ger, Ming Der ; Lan, Kuo Lung ; Lin, Chih Lung. / Effect of TiO2 nanoparticles on the improved surface-enhanced raman scattering of polypyrrole deposited on roughened gold substrates. 於: Journal of Physical Chemistry B. 2004 ; 卷 108, 編號 39. 頁 14897-14900.
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abstract = "We report here the first electrochemical oxidation-reduction cycle procedure to roughen gold substrates in 0.1 N HCl aqueous solution containing 1 mM rutile TiO2 nanoparticles under the irradiation of UV light. It is encouraging to find that the oxidized peak in the anodic scan, which is responsible for the surface-enhanced Raman scattering, increases significantly due to the effect of adding TiO2 under an electric field and UV irradiation. Moreover, the SERS spectrum of polypyrrole electrodeposited on the corresponding roughened gold substrate exhibits a 5-fold higher intensity compared to that without the contribution of TiO2 nanoparticles.",
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AU - Ger, Ming Der

AU - Lan, Kuo Lung

AU - Lin, Chih Lung

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AB - We report here the first electrochemical oxidation-reduction cycle procedure to roughen gold substrates in 0.1 N HCl aqueous solution containing 1 mM rutile TiO2 nanoparticles under the irradiation of UV light. It is encouraging to find that the oxidized peak in the anodic scan, which is responsible for the surface-enhanced Raman scattering, increases significantly due to the effect of adding TiO2 under an electric field and UV irradiation. Moreover, the SERS spectrum of polypyrrole electrodeposited on the corresponding roughened gold substrate exhibits a 5-fold higher intensity compared to that without the contribution of TiO2 nanoparticles.

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