Dendritic platinum-decorated gold nanoparticles for non-enzymatic glucose biosensing

Kuan Jung Chen, Wei Nien Su, Chun Jern Pan, Shou Yi Cheng, John Rick, Shih Han Wang, Chung Chiun Liu, Chun Chao Chang, Yaw Wen Yang, Chia Hsin Wang, Bing Joe Hwang

研究成果: 雜誌貢獻文章同行評審

23 引文 斯高帕斯(Scopus)

摘要

A bimetallic amperometric sensor comprising a dendritic Pt shell formed on rod-shaped Au cores (Aurod@Pt) for the rapid estimation of glucose by direct electro-oxidation under physiological conditions is reported. The materials were characterized by XRD, TEM, UV-vis, and cyclic voltammetry. The sensor was constructed by immobilizing Aurod@Pt bimetallic nanoparticles, in a Nafion film, on a glassy carbon electrode (Nafion/Au rod@Pt/GCE). The results showed that Aurod@Pt nanoparticles provided significantly higher sensitivity compared to dendritic Pt. X-ray absorption spectroscopy and X-ray photoelectron spectroscopy suggested that electron transfer, from the Au core to dendritic Pt, resulted in significant enhancement of electrocatalytic activity, due to reduction in Pt absorption of glucose oxidation intermediates and Cl- ions. In addition, Nafion/Aurod@Pt/GCE was found to exhibit a low working potential, fast amperometric response, high sensitivity, good reproducibility, good long term stability, and a high specificity to glucose with negligible interference from uric acid, ascorbic acid, acetamidophenol, or chloride ions.

原文英語
頁(從 - 到)5925-5932
頁數8
期刊Journal of Materials Chemistry B
1
發行號43
DOIs
出版狀態已發佈 - 十二月 21 2013

ASJC Scopus subject areas

  • 化學 (全部)
  • 生物醫學工程
  • 醫藥 (全部)
  • 材料科學(全部)

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