Catalytic Oxidation of Light Alkanes Mediated at Room Temperature by a Tricopper Cluster Complex Immobilized in Mesoporous Silica Nanoparticles

Chih Cheng Liu, Damodar Janmanchi, Da Ren Wen, Jung Nan Oung, Chung Yuan Mou, Steve S.F. Yu, Sunney I. Chan

研究成果: 雜誌貢獻文章同行評審

13 引文 斯高帕斯(Scopus)

摘要

The controlled oxidation of light alkanes is challenging chemistry. Here, we describe the further development of a catalytic system consisting of a tricopper cluster complex immobilized in mesoporous silica nanoparticles, which we have recently shown to be capable of efficient conversion of methane into methanol without overoxidation under ambient conditions, to follow the oxidation of (i) ethane to ethanol, (ii) propane to isopropanol and acetone, and (iii) a 1:1:1 mixture of methane, ethane and propane. The efficacy of the system to mediate the catalytic conversion of these light alkanes in natural gas into liquid oxidized products is also assessed.

原文英語
頁(從 - 到)5431-5440
頁數10
期刊ACS Sustainable Chemistry and Engineering
6
發行號4
DOIs
出版狀態已發佈 - 4月 2 2018
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)
  • 環境化學
  • 化學工程 (全部)
  • 可再生能源、永續發展與環境

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