(Ba,Sr)Y2Si2Al2O2N 5:Eu2+: A novel near-ultraviolet converting green phosphor for white light-emitting diodes

Wei Ren Liu, Chiao Wen Yeh, Chien Hao Huang, Chun Che Lin, Yi Chen Chiu, Yao Tsung Yeh, Ru Shi Liu

研究成果: 雜誌貢獻文章

82 引文 (Scopus)

摘要

A highly intense green-emitting phosphor BaY2Si 2Al2O2N5:Eu2+ (BYN:Eu2+) peaking at 511 nm was synthesized by a solid state reaction. The structure refinement, luminescence properties of BYN:Eu 2+ phosphors as well as their thermal quenching and the fabrication of white-light-emitting diodes (W-LEDs) were firstly investigated. By partially substituting Ba by Sr, namely (Ba,Sr)Y2Si2Al 2O2N5:Eu2+ (BSYN:Eu2+), the emission peak was shifted to 565 nm, giving a yellow-orange color, due to the splitting of the 5d energy level. By utilizing a mixture of blue-emitting BaMgAl10O17:Eu2+, green-emitting BYN:Eu 2+ and red-emitting CaAlSiN3:Eu2+ phosphors as light converters, an intense white GaN-based n-UV-LED (380 nm) was fabricated to a exhibit good color-rendering index Ra of 84.5 at a correlated color temperature of 5089 K and CIE coordinates of (0.3425, 0.3478). Based on these results, we are currently evaluating the potential application of BYN:Eu2+ as a green-emitting near-UV convertible phosphor.
原文英語
頁(從 - 到)3740-3744
頁數5
期刊Journal of Materials Chemistry
21
發行號11
DOIs
出版狀態已發佈 - 三月 21 2011
對外發佈Yes

指紋

Phosphors
Light emitting diodes
Color
Solid state reactions
Electron energy levels
Luminescence
Quenching
Fabrication
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

引用此文

(Ba,Sr)Y2Si2Al2O2N 5:Eu2+ : A novel near-ultraviolet converting green phosphor for white light-emitting diodes. / Liu, Wei Ren; Yeh, Chiao Wen; Huang, Chien Hao; Lin, Chun Che; Chiu, Yi Chen; Yeh, Yao Tsung; Liu, Ru Shi.

於: Journal of Materials Chemistry, 卷 21, 編號 11, 21.03.2011, p. 3740-3744.

研究成果: 雜誌貢獻文章

Liu, Wei Ren ; Yeh, Chiao Wen ; Huang, Chien Hao ; Lin, Chun Che ; Chiu, Yi Chen ; Yeh, Yao Tsung ; Liu, Ru Shi. / (Ba,Sr)Y2Si2Al2O2N 5:Eu2+ : A novel near-ultraviolet converting green phosphor for white light-emitting diodes. 於: Journal of Materials Chemistry. 2011 ; 卷 21, 編號 11. 頁 3740-3744.
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abstract = "A highly intense green-emitting phosphor BaY2Si 2Al2O2N5:Eu2+ (BYN:Eu2+) peaking at 511 nm was synthesized by a solid state reaction. The structure refinement, luminescence properties of BYN:Eu 2+ phosphors as well as their thermal quenching and the fabrication of white-light-emitting diodes (W-LEDs) were firstly investigated. By partially substituting Ba by Sr, namely (Ba,Sr)Y2Si2Al 2O2N5:Eu2+ (BSYN:Eu2+), the emission peak was shifted to 565 nm, giving a yellow-orange color, due to the splitting of the 5d energy level. By utilizing a mixture of blue-emitting BaMgAl10O17:Eu2+, green-emitting BYN:Eu 2+ and red-emitting CaAlSiN3:Eu2+ phosphors as light converters, an intense white GaN-based n-UV-LED (380 nm) was fabricated to a exhibit good color-rendering index Ra of 84.5 at a correlated color temperature of 5089 K and CIE coordinates of (0.3425, 0.3478). Based on these results, we are currently evaluating the potential application of BYN:Eu2+ as a green-emitting near-UV convertible phosphor.",
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