Applying mass transfer models for controlling organic compounds in ozonation process

Pen Chi Chiang, Ya Wen Ko, Yao Ming Yang, E. E. Chang

研究成果: 雜誌貢獻文章

2 引文 (Scopus)

摘要

Mass transfer plays a significant role in the ozonation process. The prediction models associated with the volumetric overall mass transfer coefficient (K(L)a) and initial fractional ozone absorption (FOA0) during the ozonation process were developed through the use of dimensional analysis. It was found that the volumetric overall mass transfer coefficient is the function of diffusivity, agitation speed, and gas flow rate, and the parameters in the K(L)a equation are determined. Application of the prediction models for K(L)a and FOA0 would yield information to choose the most practically feasible operating parameters. The removability of total organic carbon (TOC) can be estimated based on the mass balance relationship and kinetic expression of TOC oxidation, during continuous laboratory ozonation of humic acid solution. The reaction rate constant averaged 0.0291 L/mg·min. The developed model in combination with the mass transfer and reaction kinetics can be used successfully in forecasting the most efficient agitation speed to control the formation of organic compounds. Also, the critical value of ozone partial pressure to achieve the highest TOC removability can be determined through the use of the above developed model.
原文英語
頁(從 - 到)819-828
頁數10
期刊Environment International
23
發行號6
DOIs
出版狀態已發佈 - 十一月 1997

指紋

Ozonization
Organic compounds
mass transfer
organic compound
Mass transfer
Organic carbon
total organic carbon
Ozone
ozone
Humic Substances
reaction kinetics
prediction
partial pressure
gas flow
Reaction kinetics
Partial pressure
reaction rate
humic acid
diffusivity
Reaction rates

ASJC Scopus subject areas

  • Environmental Science(all)
  • Environmental Chemistry

引用此文

Applying mass transfer models for controlling organic compounds in ozonation process. / Chiang, Pen Chi; Ko, Ya Wen; Yang, Yao Ming; Chang, E. E.

於: Environment International, 卷 23, 編號 6, 11.1997, p. 819-828.

研究成果: 雜誌貢獻文章

Chiang, Pen Chi ; Ko, Ya Wen ; Yang, Yao Ming ; Chang, E. E. / Applying mass transfer models for controlling organic compounds in ozonation process. 於: Environment International. 1997 ; 卷 23, 編號 6. 頁 819-828.
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