Al2O3-modified surface-enhanced Raman scattering-active gold nanoparticles on substrates by using sonoelectrochemical pulse deposition

Chun Chao Chang, Chung Chin Yu, Yu Chuan Liu, Kuang Hsuan Yang

研究成果: 雜誌貢獻文章同行評審

5 引文 斯高帕斯(Scopus)

摘要

As shown in the literature, many methods have been developed to improve signals, reproducibility and stabilities of surface-enhanced Raman scattering (SERS) for their reliable applications. However, the fabrication can be laborious. In this work, we propose a simple pathway to prepare SERS-active substrates with Al2O3-modified Au nanoparticles (NPs) by sonoelectrochemical deposition-dissolution cycles (SEDDCs). Based on probe molecules of Rhodamine 6G (R6G), an enhancement factor of 4.4 × 10 8 and a detection limit of 2 × 10-14 M were observed on the proposed SERS-active substrates. The reproducibility and stabilities of the proposed SERS-active substrates are satisfactory. Also, the prepared Al 2O3-modified Au NPs-deposited substrate can markedly improve the thermal stability by raising the operation temperature over 50 C, as compared with unmodified Au NPs-deposited substrate. Meanwhile, aging of SERS effect observed on this proposed substrate is slight in an atmosphere of 50% RH and 20% (v/v) O2 at 30°C for 60 day.

原文英語
頁(從 - 到)38-44
頁數7
期刊Journal of Electroanalytical Chemistry
696
DOIs
出版狀態已發佈 - 2013

ASJC Scopus subject areas

  • 化學工程 (全部)
  • 分析化學
  • 電化學

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