Accelerated carbonation of steelmaking slags in a high-gravity rotating packed bed

E. E. Chang, Shu Yuan Pan, Yi Hung Chen, Chung Sung Tan, Pen Chi Chiang

研究成果: 雜誌貢獻文章同行評審

123 引文 斯高帕斯(Scopus)

摘要

Carbon dioxide (CO 2) sequestration using the accelerated carbonation of basic oxygen furnace (BOF) slag in a high-gravity rotating packed bed (RPB) under various operational conditions was investigated. The effects of reaction time, reaction temperature, rotation speed and slurry flow rate on the CO 2 sequestration process were evaluated. The samples of reacted slurry were analyzed quantitatively using thermogravimetric analysis (TGA) and atomic absorption spectrometry (AAS) and qualitatively using X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), and transmission electron microscopy (TEM). The sequestration experiments were performed at a liquid-to-solid ratio of 20:1 with a flow rate of 2.5Lmin -1 of a pure CO 2 stream under atmospheric temperature and pressure. The results show that a maximum conversion of BOF slag was 93.5% at a reaction time of 30min and a rotation speed of 750rpm at 65°C. The experimental data were utilized to determine the rate-limiting mechanism based on the shrinking core model (SCM), which was validated by the observations of SEM and TEM. Accelerated carbonation in a RPB was confirmed to be a viable method due to its higher mass-transfer rate.
原文英語
頁(從 - 到)97-106
頁數10
期刊Journal of Hazardous Materials
227-228
DOIs
出版狀態已發佈 - 八月 15 2012

ASJC Scopus subject areas

  • 健康、毒理學和誘變
  • 污染
  • 廢物管理和處置
  • 環境化學
  • 環境工程

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