A linear metal string [Cr77-teptra)4Cl2] complex with delocalized heptachromium(II) multiple bonds (teptraH3 = tetrapyridyltriamine)

Yu Hua Chen, Chung Chou Lee, Chih Chieh Wang, Gene Hsiang Lee, Shie Yang Lai, Feng Yin Li, Chung Yuan Mou, Shie Ming Peng

研究成果: 雜誌貢獻文章同行評審

82 引文 斯高帕斯(Scopus)

摘要

A heptachromium(II) metal chain helically wrapped by four all-syn type teptra3- ligands with delocalized Cr(II)-Cr(II)-Cr(II)-Cr(II)-Cr(II)-Cr(II)-Cr(II) multiple bonds is found in the complex [Cr77-teptra)4Cl2]. The band structure of a hypothetical one-dimensional chromium string based on this structure is calculated and shows metallic behavior for the string structure.

原文英語
頁(從 - 到)1667-1668
頁數2
期刊Chemical Communications
發行號17
DOIs
出版狀態已發佈 - 9月 7 1999
對外發佈

ASJC Scopus subject areas

  • 催化
  • 電子、光磁材料
  • 陶瓷和複合材料
  • 化學 (全部)
  • 表面、塗料和薄膜
  • 金屬和合金
  • 材料化學

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