A comparative study of the magnetic and microwave properties of Al3+ and In3+ substituted Mg-Mn ferrites

Chien Yie Tsay, Shan Chien Liang, Chien Ming Lei, Chung Chieh Chang

研究成果: 雜誌貢獻文章

18 引文 斯高帕斯(Scopus)

摘要

The effect of substitution of diamagnetic Al3+ and In3+ ions for partial Fe3+ ions in a spinel lattice on the magnetic and microwave properties of magnesium-manganese (Mg-Mn) ferrites has been studied. Three kinds of Mg-Mn based ferrites with compositions of Mg0.9Mn0.1Fe2O4, Mg0.9Mn0.1Al0.1Fe1.9O4, and Mg0.9Mn0.1In0.1Fe1.9O4 were prepared by the solid-state reaction route. Each mixture of high-purity starting materials (oxide powders) in stoichiometric amounts was calcined at 1100 °C for 4 h, and the debinded green compacts were sintered at 1350 °C for 4 h. XRD examination confirmed that the sintered ferrite samples had a single-phase cubic spinel structure. The incorporation of Al3+ or In3+ ions in place of Fe3+ ions in Mg-Mn ferrites increased the average particle size, decreased the Curie temperature, and resulted in a broader resonance linewidth as compared to un-substituted Mg-Mn ferrites in the X-band. In this study, the In3+ substituted Mg-Mn ferrites exhibited the highest saturation magnetization of 35.7 emu/g, the lowest coercivity of 4.1 Oe, and the highest Q×f value of 1050 GHz at a frequency of 6.5 GHz.
原文英語
頁(從 - 到)4748-4753
頁數6
期刊Ceramics International
42
發行號4
DOIs
出版狀態已發佈 - 三月 1 2016
對外發佈Yes

    指紋

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

引用此