V2O5/C3H6N6: A hybrid material with reversible lithium intercalation/deintercalation in a wide potential range

Prem Chandan, Yen Ting Chen, Tsong Ming Hsu, Yu Min Lin, Maw Kuen Wu, Hua Shu Chang, Chung Chieh Chang, Hwo Shuenn Sheu, Horng Yi Tang

Research output: Contribution to journalArticle

Abstract

The (C3H6N6)0.67V2O5 hybrid nanorods are synthesized through the self-assembly of melamine organic molecules confined by V2O5 layers and used as cathode material in the lithium-ion battery. The prepared hybrid overcomes the irreversible structure puckering problem of LixV2O5 when excess Li+, x > 1, is intercalated. It demonstrates that layered oxides combined with selective organic moieties forming an ordered structure can significantly reduce the lattice stress and structure puckering problems during lithium intercalation/deintercalation process thereby extending their cycle reversibility in the wide potential range from 1.9 to 3.5 V and reaching to x = 2 of Lix(C3H6N6)0.67V2O5. The hybrid material developed in this work tackles the structure puckering problem of V2O5 layers and opens the door for studying new battery system with greater ionic radii, such as Na+, Mg2+ and Al3+.

Original languageEnglish
Pages (from-to)A3191-A3195
JournalJournal of the Electrochemical Society
Volume164
Issue number13
DOIs
Publication statusPublished - Jan 1 2017
Externally publishedYes

Fingerprint

Melamine
Hybrid materials
Intercalation
Nanorods
Lithium
Self assembly
Cathodes
Molecules
Oxides
Lithium-ion batteries
vanadium pentoxide
melamine

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Chandan, P., Chen, Y. T., Hsu, T. M., Lin, Y. M., Wu, M. K., Chang, H. S., ... Tang, H. Y. (2017). V2O5/C3H6N6: A hybrid material with reversible lithium intercalation/deintercalation in a wide potential range. Journal of the Electrochemical Society, 164(13), A3191-A3195. https://doi.org/10.1149/2.1201713jes

V2O5/C3H6N6 : A hybrid material with reversible lithium intercalation/deintercalation in a wide potential range. / Chandan, Prem; Chen, Yen Ting; Hsu, Tsong Ming; Lin, Yu Min; Wu, Maw Kuen; Chang, Hua Shu; Chang, Chung Chieh; Sheu, Hwo Shuenn; Tang, Horng Yi.

In: Journal of the Electrochemical Society, Vol. 164, No. 13, 01.01.2017, p. A3191-A3195.

Research output: Contribution to journalArticle

Chandan, P, Chen, YT, Hsu, TM, Lin, YM, Wu, MK, Chang, HS, Chang, CC, Sheu, HS & Tang, HY 2017, 'V2O5/C3H6N6: A hybrid material with reversible lithium intercalation/deintercalation in a wide potential range', Journal of the Electrochemical Society, vol. 164, no. 13, pp. A3191-A3195. https://doi.org/10.1149/2.1201713jes
Chandan, Prem ; Chen, Yen Ting ; Hsu, Tsong Ming ; Lin, Yu Min ; Wu, Maw Kuen ; Chang, Hua Shu ; Chang, Chung Chieh ; Sheu, Hwo Shuenn ; Tang, Horng Yi. / V2O5/C3H6N6 : A hybrid material with reversible lithium intercalation/deintercalation in a wide potential range. In: Journal of the Electrochemical Society. 2017 ; Vol. 164, No. 13. pp. A3191-A3195.
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