The effect of thieno[3,2-b]thiophene on the absorption, charge mobility and photovoltaic performance of diketopyrrolopyrrole-based low bandgap conjugated polymers

Yongxi Li, Chih Yu Chang, Yu Chen, Yi Song, Chang Zhi Li, Hin Lap Yip, Alex K.Y. Jen, Chao Li

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

A series of two-dimensional diketopyrrolopyrrole-based low band gap conjugated polymers were synthesized. Replacing thiophene with thieno[3,2-b]thiophene in the side chain and bridge resulted in significant changes to the optical, electrochemical, and morphological properties of the polymers, as well as the subsequent performance of devices made from these materials. The polymer with thieno[3,2-b]thiophene as a bridge instead of a side chain exhibited an increased absorption coefficient and hole mobility, and resulted in the highest power conversion efficiency (5.34%) in this series of polymers. This finding provides valuable insight for the development of more efficient low band-gap polymers.

Original languageEnglish
Pages (from-to)7526-7533
Number of pages8
JournalJournal of Materials Chemistry C
Volume1
Issue number45
DOIs
Publication statusPublished - Dec 7 2013
Externally publishedYes

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Thiophenes
Conjugated polymers
Thiophene
Polymers
Energy gap
Hole mobility
Conversion efficiency

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

Cite this

The effect of thieno[3,2-b]thiophene on the absorption, charge mobility and photovoltaic performance of diketopyrrolopyrrole-based low bandgap conjugated polymers. / Li, Yongxi; Chang, Chih Yu; Chen, Yu; Song, Yi; Li, Chang Zhi; Yip, Hin Lap; Jen, Alex K.Y.; Li, Chao.

In: Journal of Materials Chemistry C, Vol. 1, No. 45, 07.12.2013, p. 7526-7533.

Research output: Contribution to journalArticle

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