Polymer-metal-oxide hybrid solar cells

Shao Sian Li, Chun Wei Chen

Research output: Contribution to journalReview article

45 Citations (Scopus)

Abstract

Polymer solar cells have great potential for offering a cost-effective approach for converting solar energy into electricity compared to traditional inorganic counterparts. Besides the most intensively studied materials for polymer solar cells consisting of conducting polymer and fullerene derivative hybrids, polymer-inorganic nanocrystal (NC) hybrid solar cell devices represent promising alternatives by taking advantage of the relatively high electron mobility, good physical and chemical stability and various morphologies of inorganic NCs. This paper presents a review of the current status and development of polymer-inorganic hybrid solar cells based on metal oxide NCs by focusing the discussion on TiO2 and ZnO. These metal oxide NC materials are promising acceptor candidates because they are environmentally friendly and cheap to be synthesized by using wet chemical methods with a wide range of morphologies, enabling full compatibility with the solution-processable fabrication of polymer solar cells. Substantial progress has been achieved recently in the power conversion efficiencies of polymer-metal-oxide hybrid solar cells through the control of nanoscale polymer-inorganic hybrid morphologies and the improved interfaces between polymers and inorganic nanocrystals. We also reviewed the recently developed state-of-the-art analytical techniques introduced to reveal the nanoscale morphological organization of polymers and NCs in polymer-metal-oxide hybrid solar cells, which provides the understanding of the interplay between controlling nanoscale morphologies of polymer-metal-oxide NC hybrids and photocarrier dynamics and the corresponding device performance. Finally, the main challenges in the development of polymer-metal-oxide hybrid solar cells consisting of both bulk heterojunctions (BHJs) and nanostructured hybrid device architectures are identified, and strategies for improving the device performances are also discussed.

Original languageEnglish
Pages (from-to)10574-10591
Number of pages18
JournalJournal of Materials Chemistry A
Volume1
Issue number36
DOIs
Publication statusPublished - Sep 28 2013
Externally publishedYes

Fingerprint

Oxides
Solar cells
Polymers
Metals
Inorganic polymers
Nanocrystals
Fullerenes
Electron mobility
Chemical stability
Conducting polymers
Solar energy
Conversion efficiency
Heterojunctions
Electricity
Derivatives
Fabrication
Polymer solar cells
Costs

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Polymer-metal-oxide hybrid solar cells. / Li, Shao Sian; Chen, Chun Wei.

In: Journal of Materials Chemistry A, Vol. 1, No. 36, 28.09.2013, p. 10574-10591.

Research output: Contribution to journalReview article

Li, Shao Sian ; Chen, Chun Wei. / Polymer-metal-oxide hybrid solar cells. In: Journal of Materials Chemistry A. 2013 ; Vol. 1, No. 36. pp. 10574-10591.
@article{d4ddea0098a74c8a8735833e2943666c,
title = "Polymer-metal-oxide hybrid solar cells",
abstract = "Polymer solar cells have great potential for offering a cost-effective approach for converting solar energy into electricity compared to traditional inorganic counterparts. Besides the most intensively studied materials for polymer solar cells consisting of conducting polymer and fullerene derivative hybrids, polymer-inorganic nanocrystal (NC) hybrid solar cell devices represent promising alternatives by taking advantage of the relatively high electron mobility, good physical and chemical stability and various morphologies of inorganic NCs. This paper presents a review of the current status and development of polymer-inorganic hybrid solar cells based on metal oxide NCs by focusing the discussion on TiO2 and ZnO. These metal oxide NC materials are promising acceptor candidates because they are environmentally friendly and cheap to be synthesized by using wet chemical methods with a wide range of morphologies, enabling full compatibility with the solution-processable fabrication of polymer solar cells. Substantial progress has been achieved recently in the power conversion efficiencies of polymer-metal-oxide hybrid solar cells through the control of nanoscale polymer-inorganic hybrid morphologies and the improved interfaces between polymers and inorganic nanocrystals. We also reviewed the recently developed state-of-the-art analytical techniques introduced to reveal the nanoscale morphological organization of polymers and NCs in polymer-metal-oxide hybrid solar cells, which provides the understanding of the interplay between controlling nanoscale morphologies of polymer-metal-oxide NC hybrids and photocarrier dynamics and the corresponding device performance. Finally, the main challenges in the development of polymer-metal-oxide hybrid solar cells consisting of both bulk heterojunctions (BHJs) and nanostructured hybrid device architectures are identified, and strategies for improving the device performances are also discussed.",
author = "Li, {Shao Sian} and Chen, {Chun Wei}",
year = "2013",
month = "9",
day = "28",
doi = "10.1039/c3ta11998j",
language = "English",
volume = "1",
pages = "10574--10591",
journal = "Journal of Materials Chemistry A",
issn = "2050-7488",
publisher = "Royal Society of Chemistry",
number = "36",

}

TY - JOUR

T1 - Polymer-metal-oxide hybrid solar cells

AU - Li, Shao Sian

AU - Chen, Chun Wei

PY - 2013/9/28

Y1 - 2013/9/28

N2 - Polymer solar cells have great potential for offering a cost-effective approach for converting solar energy into electricity compared to traditional inorganic counterparts. Besides the most intensively studied materials for polymer solar cells consisting of conducting polymer and fullerene derivative hybrids, polymer-inorganic nanocrystal (NC) hybrid solar cell devices represent promising alternatives by taking advantage of the relatively high electron mobility, good physical and chemical stability and various morphologies of inorganic NCs. This paper presents a review of the current status and development of polymer-inorganic hybrid solar cells based on metal oxide NCs by focusing the discussion on TiO2 and ZnO. These metal oxide NC materials are promising acceptor candidates because they are environmentally friendly and cheap to be synthesized by using wet chemical methods with a wide range of morphologies, enabling full compatibility with the solution-processable fabrication of polymer solar cells. Substantial progress has been achieved recently in the power conversion efficiencies of polymer-metal-oxide hybrid solar cells through the control of nanoscale polymer-inorganic hybrid morphologies and the improved interfaces between polymers and inorganic nanocrystals. We also reviewed the recently developed state-of-the-art analytical techniques introduced to reveal the nanoscale morphological organization of polymers and NCs in polymer-metal-oxide hybrid solar cells, which provides the understanding of the interplay between controlling nanoscale morphologies of polymer-metal-oxide NC hybrids and photocarrier dynamics and the corresponding device performance. Finally, the main challenges in the development of polymer-metal-oxide hybrid solar cells consisting of both bulk heterojunctions (BHJs) and nanostructured hybrid device architectures are identified, and strategies for improving the device performances are also discussed.

AB - Polymer solar cells have great potential for offering a cost-effective approach for converting solar energy into electricity compared to traditional inorganic counterparts. Besides the most intensively studied materials for polymer solar cells consisting of conducting polymer and fullerene derivative hybrids, polymer-inorganic nanocrystal (NC) hybrid solar cell devices represent promising alternatives by taking advantage of the relatively high electron mobility, good physical and chemical stability and various morphologies of inorganic NCs. This paper presents a review of the current status and development of polymer-inorganic hybrid solar cells based on metal oxide NCs by focusing the discussion on TiO2 and ZnO. These metal oxide NC materials are promising acceptor candidates because they are environmentally friendly and cheap to be synthesized by using wet chemical methods with a wide range of morphologies, enabling full compatibility with the solution-processable fabrication of polymer solar cells. Substantial progress has been achieved recently in the power conversion efficiencies of polymer-metal-oxide hybrid solar cells through the control of nanoscale polymer-inorganic hybrid morphologies and the improved interfaces between polymers and inorganic nanocrystals. We also reviewed the recently developed state-of-the-art analytical techniques introduced to reveal the nanoscale morphological organization of polymers and NCs in polymer-metal-oxide hybrid solar cells, which provides the understanding of the interplay between controlling nanoscale morphologies of polymer-metal-oxide NC hybrids and photocarrier dynamics and the corresponding device performance. Finally, the main challenges in the development of polymer-metal-oxide hybrid solar cells consisting of both bulk heterojunctions (BHJs) and nanostructured hybrid device architectures are identified, and strategies for improving the device performances are also discussed.

UR - http://www.scopus.com/inward/record.url?scp=84882590065&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84882590065&partnerID=8YFLogxK

U2 - 10.1039/c3ta11998j

DO - 10.1039/c3ta11998j

M3 - Review article

AN - SCOPUS:84882590065

VL - 1

SP - 10574

EP - 10591

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

SN - 2050-7488

IS - 36

ER -