Palladium-catalysed [3 + 2] cycloaddition of trimethylenemethane (TMM) and fullerene. Observation of the room-temperature fluorescence spectrum of the TMM-C60 adduct

Lung Lin Shiu, Tsung I. Lin, Shie Ming Peng, Guor Rong Her, Dar Der Ju, Syh Kun Lin, Jyun Hwei Hwang, Chung Yuan Mou, Tien Yau Luh

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

The first synthesis of the parent TMM-C60 adduct 1 was achieved by means of Pd°-mediated [3 + 2] cycloaddition and its structure was unambiguously proved by spectroscopic means (1H and 13C NMR and MS); a pentane solution of the adduct 1 exhibited a fluorescence emission spectrum with λmax 704 nm and vibronic fine structure at ambient temperature.

Original languageEnglish
Pages (from-to)647-648
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
DOIs
Publication statusPublished - 1994
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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