Novel Fluorescence Sensor Based on All-Inorganic Perovskite Quantum Dots Coated with Molecularly Imprinted Polymers for Highly Selective and Sensitive Detection of Omethoate

Shuyi Huang, Manli Guo, Jiean Tan, Yuanyuan Geng, Jinyi Wu, Youwen Tang, Chaochin Su, Chun Che Lin, Yong Liang

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

All-inorganic cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I) have attracted considerable attention with superior electrical and photophysical properties. In this study, luminescent perovskite (CsPbBr3) quantum dots (QDs) as sensing elements combined with molecularly imprinted polymers (MIPs) are used for the detection of omethoate (OMT). The new MIPs@CsPbBr3 QDs were synthesized successfully through the imprinting technology with a sol-gel reaction. The fluorescence (FL) of the MIPs@CsPbBr3 QDs was quenched obviously on loading the MIPs with OMT, the linear range of OMT was from 50 to 400 ng/mL, and the detection limit was 18.8 ng/mL. The imprinting factor was 3.2, which indicated excellent specificity of the MIPs for the inorganic metal halide (IMH) perovskites. The novel composite possesses the outstanding FL capability of CsPbBr3 QDs and the high selectivity of molecular imprinting technology, which can convert the specific interactions between template and the imprinted cavities to apparent changes in the FL intensity. Hence, a selective and simple FL sensor for direct and fast detection of organophosphorus pesticide in vegetable and soil samples was developed here. The present work also illustrates the potential of IMH perovskites for sensor applications in biological and environmental detection.

Original languageEnglish
Pages (from-to)39056-39063
Number of pages8
JournalACS Applied Materials and Interfaces
Volume10
Issue number45
DOIs
Publication statusPublished - Nov 14 2018

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Perovskite
Semiconductor quantum dots
Polymers
Fluorescence
Sensors
Metal halides
Cesium
Vegetables
Pesticides
Sol-gels
dimethoxon
perovskite
Soils
Composite materials

Keywords

  • CsPbBr
  • fluorescent sensor
  • inorganic perovskites
  • molecular imprinting
  • omethoate

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Novel Fluorescence Sensor Based on All-Inorganic Perovskite Quantum Dots Coated with Molecularly Imprinted Polymers for Highly Selective and Sensitive Detection of Omethoate. / Huang, Shuyi; Guo, Manli; Tan, Jiean; Geng, Yuanyuan; Wu, Jinyi; Tang, Youwen; Su, Chaochin; Lin, Chun Che; Liang, Yong.

In: ACS Applied Materials and Interfaces, Vol. 10, No. 45, 14.11.2018, p. 39056-39063.

Research output: Contribution to journalArticle

Huang, Shuyi ; Guo, Manli ; Tan, Jiean ; Geng, Yuanyuan ; Wu, Jinyi ; Tang, Youwen ; Su, Chaochin ; Lin, Chun Che ; Liang, Yong. / Novel Fluorescence Sensor Based on All-Inorganic Perovskite Quantum Dots Coated with Molecularly Imprinted Polymers for Highly Selective and Sensitive Detection of Omethoate. In: ACS Applied Materials and Interfaces. 2018 ; Vol. 10, No. 45. pp. 39056-39063.
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