Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells

Yih Chun Chen; Shao Ku Huang; Shao Sian Li; Yao Yu Tsai; Chih Ping Chen; Yuan Jay Chang

doi:10.23919/AM-FPD.2018.8437119

Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells

Yih Chun Chen, Shao Ku Huang, Shao Sian Li, Yao Yu Tsai, Chih Ping Chen, Yuan Jay Chang

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R _s , and R _sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J _sc of 22.18 mA.cm ^-2 , V _oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06%, which was similar to that of spiro-OMeTAD (16.08%). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional.

Original language	English
Title of host publication	AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices
Subtitle of host publication	TFT Technologies and FPD Materials, Proceedings
Publisher	Institute of Electrical and Electronics Engineers Inc.
ISBN (Print)	9784990875350
DOIs	https://doi.org/10.23919/AM-FPD.2018.8437119
Publication status	Published - Aug 15 2018
Event	25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018 - Kyoto, Japan Duration: Jul 3 2018 → Jul 6 2018

Publication series

Name	AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings

Conference

Conference	25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018
Country/Territory	Japan
City	Kyoto
Period	7/3/18 → 7/6/18

ASJC Scopus subject areas

Media Technology
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.23919/AM-FPD.2018.8437119

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Chen, Y. C., Huang, S. K., Li, S. S., Tsai, Y. Y., Chen, C. P., & Chang, Y. J. (2018). Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. In AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings [8437119] (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.23919/AM-FPD.2018.8437119

Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. / Chen, Yih Chun; Huang, Shao Ku; Li, Shao Sian et al.

AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc., 2018. 8437119 (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Chen, YC, Huang, SK, Li, SS, Tsai, YY, Chen, CP & Chang, YJ 2018, Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. in AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings., 8437119, AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings, Institute of Electrical and Electronics Engineers Inc., 25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018, Kyoto, Japan, 7/3/18. https://doi.org/10.23919/AM-FPD.2018.8437119

Chen YC, Huang SK, Li SS, Tsai YY, Chen CP, Chang YJ. Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. In AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc. 2018. 8437119. (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings). doi: 10.23919/AM-FPD.2018.8437119

Chen, Yih Chun ; Huang, Shao Ku ; Li, Shao Sian et al. / Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc., 2018. (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings).

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title = "Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells",

abstract = " This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R s , and R sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J sc of 22.18 mA.cm -2 , V oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06%, which was similar to that of spiro-OMeTAD (16.08%). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional. ",

author = "Chen, {Yih Chun} and Huang, {Shao Ku} and Li, {Shao Sian} and Tsai, {Yao Yu} and Chen, {Chih Ping} and Chang, {Yuan Jay}",

note = "Funding Information: (MOST 106-2113-M-029 -001 -) is gratefully acknowledged. Publisher Copyright: {\textcopyright} 2018 FTFMD. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.; 25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018 ; Conference date: 03-07-2018 Through 06-07-2018",

year = "2018",

month = aug,

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doi = "10.23919/AM-FPD.2018.8437119",

language = "English",

isbn = "9784990875350",

series = "AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings",

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AU - Chen, Yih Chun

AU - Huang, Shao Ku

AU - Li, Shao Sian

AU - Tsai, Yao Yu

AU - Chen, Chih Ping

AU - Chang, Yuan Jay

PY - 2018/8/15

Y1 - 2018/8/15

N2 - This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R s , and R sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J sc of 22.18 mA.cm -2 , V oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06%, which was similar to that of spiro-OMeTAD (16.08%). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional.

AB - This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R s , and R sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J sc of 22.18 mA.cm -2 , V oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06%, which was similar to that of spiro-OMeTAD (16.08%). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional.

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ER -

Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells

Abstract

Publication series

Conference

ASJC Scopus subject areas

UN SDGs

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