Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells

Yih Chun Chen, Shao Ku Huang, Shao Sian Li, Yao Yu Tsai, Chih Ping Chen, Yuan Jay Chang

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R s , and R sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J sc of 22.18 mA.cm -2 , V oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06%, which was similar to that of spiro-OMeTAD (16.08%). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional.

Original languageEnglish
Title of host publicationAM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices
Subtitle of host publicationTFT Technologies and FPD Materials, Proceedings
PublisherInstitute of Electrical and Electronics Engineers Inc.
ISBN (Print)9784990875350
DOIs
Publication statusPublished - Aug 15 2018
Event25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018 - Kyoto, Japan
Duration: Jul 3 2018Jul 6 2018

Publication series

NameAM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings

Conference

Conference25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018
CountryJapan
CityKyoto
Period7/3/187/6/18

Fingerprint

solar cells
Hole mobility
hole mobility
linkages
Conversion efficiency
Density functional theory
fluorene
Perovskite solar cells
density functional theory
Costs

ASJC Scopus subject areas

  • Media Technology
  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics

Cite this

Chen, Y. C., Huang, S. K., Li, S. S., Tsai, Y. Y., Chen, C. P., & Chang, Y. J. (2018). Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. In AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings [8437119] (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.23919/AM-FPD.2018.8437119

Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. / Chen, Yih Chun; Huang, Shao Ku; Li, Shao Sian; Tsai, Yao Yu; Chen, Chih Ping; Chang, Yuan Jay.

AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc., 2018. 8437119 (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Chen, YC, Huang, SK, Li, SS, Tsai, YY, Chen, CP & Chang, YJ 2018, Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. in AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings., 8437119, AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings, Institute of Electrical and Electronics Engineers Inc., 25th International Workshop on Active-Matrix Flatpanel Displays and Devices - TFT Technologies and FPD Materials, AM-FPD 2018, Kyoto, Japan, 7/3/18. https://doi.org/10.23919/AM-FPD.2018.8437119
Chen YC, Huang SK, Li SS, Tsai YY, Chen CP, Chang YJ. Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. In AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc. 2018. 8437119. (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings). https://doi.org/10.23919/AM-FPD.2018.8437119
Chen, Yih Chun ; Huang, Shao Ku ; Li, Shao Sian ; Tsai, Yao Yu ; Chen, Chih Ping ; Chang, Yuan Jay. / Novel Facilely Synthesized spiro[Fluorene-9,9′-phenanthren-10′-one] in D-A-D Hole-transporting Materials for Perovskite Solar Cells. AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings. Institute of Electrical and Electronics Engineers Inc., 2018. (AM-FPD 2018 - 25th International Workshop on Active-Matrix Flatpanel Displays and Devices: TFT Technologies and FPD Materials, Proceedings).
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abstract = "This is the first report of donor-acceptor-donor (D-A-D) hole-transporting materials (HTMs) with spiro linkage in perovskite solar cells (PSCs). We demonstrated two novel D-A-D type HTMs with spiro[fluorene-9,9′-phenanthren-10′-one] as the core structure. Yih-series HTMs achieved low cost, high yield, and ease of operation. Yih-2 achieved slightly higher R s , and R sh , and hole mobility can enhance the performance of PSCs. Yih-2 exhibited higher Voc and. Z, than did Yih-l. We discuss the photovoltaic performance of PSCs. Consequently, Yih-2 as an HTM in PSCs achieved J sc of 22.18 mA.cm -2 , V oc of 1.02 V, and fill factor of 0.71, corresponding to an overall conversion efficiency of 16.06{\%}, which was similar to that of spiro-OMeTAD (16.08{\%}). The photophysical properties of HTMs were analyzed through time-dependent density functional theory with the B3LYP functional.",
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