Nafion ionomer/conjugated ionic polyacetylene matrix composite

Chien C. Chen, Jo Ann Ratto, Rita B. Blumstein

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

Polymer matrix composites are prepared by incorporating a highly conjugated substituted polyacetylene into a Nafion ionomer membrane. The monomer, 2-ethynylpyridine (2EP) is quaternized within the ionic domains of Nafion. An in-situ polymerization occurs upon heating the membranes which contain 5-15% by weight of 2EP. Dynamic mechanical analysis and thermogravimetric analysis studies indicate that the mechanical properties and thermal stability of the composites are superior to Nafion. Gas permeability coefficients of O2 and N2 are measured. Preliminary results indicate significant increase in the separation factor (α = PeO2/PeN2) within the composite.

Original languageEnglish
Title of host publicationAnnual Technical Conference - ANTEC, Conference Proceedings
PublisherSoc of Plastics Engineers
Pages1443-1446
Number of pages4
Volume2
Publication statusPublished - 1995
Externally publishedYes
EventProceedings of the 53rd Annual Technical Conference. Part 1 (of 3) - Boston, MA, USA
Duration: May 7 1995Oct 11 1995

Other

OtherProceedings of the 53rd Annual Technical Conference. Part 1 (of 3)
CityBoston, MA, USA
Period5/7/9510/11/95

Fingerprint

Polyacetylenes
Ionomers
Membranes
Polymer matrix composites
Gas permeability
Hydraulic conductivity
Composite materials
Dynamic mechanical analysis
Thermogravimetric analysis
Thermodynamic stability
Monomers
Polymerization
Heating
Mechanical properties

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Chen, C. C., Ratto, J. A., & Blumstein, R. B. (1995). Nafion ionomer/conjugated ionic polyacetylene matrix composite. In Annual Technical Conference - ANTEC, Conference Proceedings (Vol. 2, pp. 1443-1446). Soc of Plastics Engineers.

Nafion ionomer/conjugated ionic polyacetylene matrix composite. / Chen, Chien C.; Ratto, Jo Ann; Blumstein, Rita B.

Annual Technical Conference - ANTEC, Conference Proceedings. Vol. 2 Soc of Plastics Engineers, 1995. p. 1443-1446.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Chen, CC, Ratto, JA & Blumstein, RB 1995, Nafion ionomer/conjugated ionic polyacetylene matrix composite. in Annual Technical Conference - ANTEC, Conference Proceedings. vol. 2, Soc of Plastics Engineers, pp. 1443-1446, Proceedings of the 53rd Annual Technical Conference. Part 1 (of 3), Boston, MA, USA, 5/7/95.
Chen CC, Ratto JA, Blumstein RB. Nafion ionomer/conjugated ionic polyacetylene matrix composite. In Annual Technical Conference - ANTEC, Conference Proceedings. Vol. 2. Soc of Plastics Engineers. 1995. p. 1443-1446
Chen, Chien C. ; Ratto, Jo Ann ; Blumstein, Rita B. / Nafion ionomer/conjugated ionic polyacetylene matrix composite. Annual Technical Conference - ANTEC, Conference Proceedings. Vol. 2 Soc of Plastics Engineers, 1995. pp. 1443-1446
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AB - Polymer matrix composites are prepared by incorporating a highly conjugated substituted polyacetylene into a Nafion ionomer membrane. The monomer, 2-ethynylpyridine (2EP) is quaternized within the ionic domains of Nafion. An in-situ polymerization occurs upon heating the membranes which contain 5-15% by weight of 2EP. Dynamic mechanical analysis and thermogravimetric analysis studies indicate that the mechanical properties and thermal stability of the composites are superior to Nafion. Gas permeability coefficients of O2 and N2 are measured. Preliminary results indicate significant increase in the separation factor (α = PeO2/PeN2) within the composite.

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