Method of evaluating the ionic conductance of polypyrrole films and improvement of ionic conductance of polyethylene oxide-incorporated polypyrrole composite

Yu Chuan Liu

doi:10.1016/S0254-0584(02)00168-2

Method of evaluating the ionic conductance of polypyrrole films and improvement of ionic conductance of polyethylene oxide-incorporated polypyrrole composite

Yu Chuan Liu

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

In this study, stainless steel electrode alternate current (ac) impedance associated with direct current (dc) polarization measurements were proposed to successfully evaluate the contribution of ionic conductance (t^ion) to the bulk conductance of polypyrrole (PPy) in various relative humidities (RH). The fraction of t^ion, defined as the ratio of (1/R_i) to ((1/R_i)+(1/R_e)), was used as a quantitative index for the contribution of ionic conductance. The results showed that the t^ion are 0.15, 0.29, and 0.46 for PPy in 5, 25, and 50% RH, respectively. Also, the t^ion can increase from 0.12 to 0.22 in dry nitrogen after PPy was modified with polyethylene oxide (PEO).

Original language	English
Pages (from-to)	791-795
Number of pages	5
Journal	Materials Chemistry and Physics
Volume	77
Issue number	3
DOIs	https://doi.org/10.1016/S0254-0584(02)00168-2
Publication status	Published - Jan 30 2003
Externally published	Yes

Keywords

Fraction of ionic conductance
Ionic conductance
Polyethylene oxide
Polypyrrole

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics

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10.1016/S0254-0584(02)00168-2

Cite this

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title = "Method of evaluating the ionic conductance of polypyrrole films and improvement of ionic conductance of polyethylene oxide-incorporated polypyrrole composite",

abstract = "In this study, stainless steel electrode alternate current (ac) impedance associated with direct current (dc) polarization measurements were proposed to successfully evaluate the contribution of ionic conductance (tion) to the bulk conductance of polypyrrole (PPy) in various relative humidities (RH). The fraction of tion, defined as the ratio of (1/Ri) to ((1/Ri)+(1/Re)), was used as a quantitative index for the contribution of ionic conductance. The results showed that the tion are 0.15, 0.29, and 0.46 for PPy in 5, 25, and 50% RH, respectively. Also, the tion can increase from 0.12 to 0.22 in dry nitrogen after PPy was modified with polyethylene oxide (PEO).",

keywords = "Fraction of ionic conductance, Ionic conductance, Polyethylene oxide, Polypyrrole",

author = "Liu, {Yu Chuan}",

note = "Funding Information: The author thanks the National Science Council of the Republic of China (NSC-89-2214-E-238-001) and Van Nung Institute of Technology for their financial support.",

year = "2003",

month = jan,

day = "30",

doi = "10.1016/S0254-0584(02)00168-2",

language = "English",

volume = "77",

pages = "791--795",

journal = "Materials Chemistry and Physics",

issn = "0254-0584",

publisher = "Elsevier BV",

number = "3",

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TY - JOUR

T1 - Method of evaluating the ionic conductance of polypyrrole films and improvement of ionic conductance of polyethylene oxide-incorporated polypyrrole composite

AU - Liu, Yu Chuan

N1 - Funding Information: The author thanks the National Science Council of the Republic of China (NSC-89-2214-E-238-001) and Van Nung Institute of Technology for their financial support.

PY - 2003/1/30

Y1 - 2003/1/30

N2 - In this study, stainless steel electrode alternate current (ac) impedance associated with direct current (dc) polarization measurements were proposed to successfully evaluate the contribution of ionic conductance (tion) to the bulk conductance of polypyrrole (PPy) in various relative humidities (RH). The fraction of tion, defined as the ratio of (1/Ri) to ((1/Ri)+(1/Re)), was used as a quantitative index for the contribution of ionic conductance. The results showed that the tion are 0.15, 0.29, and 0.46 for PPy in 5, 25, and 50% RH, respectively. Also, the tion can increase from 0.12 to 0.22 in dry nitrogen after PPy was modified with polyethylene oxide (PEO).

AB - In this study, stainless steel electrode alternate current (ac) impedance associated with direct current (dc) polarization measurements were proposed to successfully evaluate the contribution of ionic conductance (tion) to the bulk conductance of polypyrrole (PPy) in various relative humidities (RH). The fraction of tion, defined as the ratio of (1/Ri) to ((1/Ri)+(1/Re)), was used as a quantitative index for the contribution of ionic conductance. The results showed that the tion are 0.15, 0.29, and 0.46 for PPy in 5, 25, and 50% RH, respectively. Also, the tion can increase from 0.12 to 0.22 in dry nitrogen after PPy was modified with polyethylene oxide (PEO).

KW - Fraction of ionic conductance

KW - Ionic conductance

KW - Polyethylene oxide

KW - Polypyrrole

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UR - http://www.scopus.com/inward/citedby.url?scp=0037472289&partnerID=8YFLogxK

U2 - 10.1016/S0254-0584(02)00168-2

DO - 10.1016/S0254-0584(02)00168-2

M3 - Article

AN - SCOPUS:0037472289

VL - 77

SP - 791

EP - 795

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

SN - 0254-0584

IS - 3

ER -

Method of evaluating the ionic conductance of polypyrrole films and improvement of ionic conductance of polyethylene oxide-incorporated polypyrrole composite

Abstract

Keywords

ASJC Scopus subject areas

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