Mass spectra of N-substituted cantharidinimides

Pen Y. Lin, Shaw T. Lin, David W M Liang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The mass spectra of a series of N-substituted cantharidinimides were examined. The feature of this series compounds is a sequential double hydrogen transfer from the oxabicycloheptane unit to either the carbonyl group of the succinimide unit or the nitrogen atom of the pyridyl or thiazolyl substituent through space. The ability of the N-substituent to accept a hydrogen atom possibly leads to the different fragmentation pathway.

Original languageEnglish
Pages (from-to)153-157
Number of pages5
JournalJournal of Mass Spectrometry
Volume39
Issue number2
DOIs
Publication statusPublished - Feb 2004

Keywords

  • Cantharidin
  • Hydrogen transfer
  • N-substituted cantharidinimides

ASJC Scopus subject areas

  • Organic Chemistry
  • Spectroscopy
  • Biophysics

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