Manganese(III) acetate mediated oxidation of aporphines: a convenient and useful synthesis of oxoaporphines

Om V. Singh, Wei Jan Huang, Chung Hsiung Chen, Shoei Sheng Lee

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Manganese(III) acetate mediated oxidation of aporphines to oxoaporphines is described. The developed methodology was conveniently applied for the synthesis of naturally occurring oxoaporphine alkaloids, oxoglaucine, and atheroline, starting from commercially available boldine.

Original languageEnglish
Pages (from-to)8166-8169
Number of pages4
JournalTetrahedron Letters
Volume48
Issue number46
DOIs
Publication statusPublished - Nov 12 2007
Externally publishedYes

Fingerprint

Aporphines
Alkaloids
Oxidation
boldine
manganese(III) acetate dihydrate
oxoglaucine
atheroline

Keywords

  • Aporphines
  • Atheroline
  • Iodobenzene diacetate
  • Isoquinoline alkaloids
  • Manganese(III) acetate
  • Oxoaporphine
  • Oxoglaucine

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Manganese(III) acetate mediated oxidation of aporphines : a convenient and useful synthesis of oxoaporphines. / Singh, Om V.; Huang, Wei Jan; Chen, Chung Hsiung; Lee, Shoei Sheng.

In: Tetrahedron Letters, Vol. 48, No. 46, 12.11.2007, p. 8166-8169.

Research output: Contribution to journalArticle

Singh, Om V. ; Huang, Wei Jan ; Chen, Chung Hsiung ; Lee, Shoei Sheng. / Manganese(III) acetate mediated oxidation of aporphines : a convenient and useful synthesis of oxoaporphines. In: Tetrahedron Letters. 2007 ; Vol. 48, No. 46. pp. 8166-8169.
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