Improvement in anti-aging of metallized Nafion® hydrogen sensors modified by chemical vapor deposition of polypyrrole

Yu Chuan Liu; Bing Joe Hwang; Wen Cheng Hsu

doi:10.1016/S0925-4005(02)00250-2

Improvement in anti-aging of metallized Nafion® hydrogen sensors modified by chemical vapor deposition of polypyrrole

Yu Chuan Liu, Bing Joe Hwang, Wen Cheng Hsu

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Pt/Nafion® and Pd/Nafion® electrodes were prepared by impregnation-reduction methods in detecting hydrogen. For improving their anti-aging abilities, polypyrrole (PPy) films were chemically deposited onto the metallized electrodes. After continuously aging tests for 48 h, the sensitivities of the Pt/Nafion® and the PPy-modified Pt/Nafion® electrodes decrease by 68 and 32%, respectively, but the accompanying sacrifice is the loss in sensitivity from 0.0744 to 0.0261 μA/ppm. Similarly, the sensitivities of the Pd/Nafion® and the PPy-modified Pd/Nafion® electrodes decrease by 84 and 68%, respectively, accompanying with the sacrifice of loss in sensitivity from 0.0519 to 0.0262 μA/ppm.

Original language	English
Pages (from-to)	304-308
Number of pages	5
Journal	Sensors and Actuators, B: Chemical
Volume	87
Issue number	2
DOIs	https://doi.org/10.1016/S0925-4005(02)00250-2
Publication status	Published - Dec 10 2002
Externally published	Yes

Keywords

Aging
Chemical vapor deposition
Metallized Nafion® electrodes
Polypyrrole modification

ASJC Scopus subject areas

Analytical Chemistry
Electrochemistry
Electrical and Electronic Engineering

Access to Document

10.1016/S0925-4005(02)00250-2

Fingerprint Dive into the research topics of 'Improvement in anti-aging of metallized Nafion® hydrogen sensors modified by chemical vapor deposition of polypyrrole'. Together they form a unique fingerprint.

Cite this

@article{06763e9c3a9746f5becb193d76ae6d64,

title = "Improvement in anti-aging of metallized Nafion{\textregistered} hydrogen sensors modified by chemical vapor deposition of polypyrrole",

abstract = "Pt/Nafion{\textregistered} and Pd/Nafion{\textregistered} electrodes were prepared by impregnation-reduction methods in detecting hydrogen. For improving their anti-aging abilities, polypyrrole (PPy) films were chemically deposited onto the metallized electrodes. After continuously aging tests for 48 h, the sensitivities of the Pt/Nafion{\textregistered} and the PPy-modified Pt/Nafion{\textregistered} electrodes decrease by 68 and 32%, respectively, but the accompanying sacrifice is the loss in sensitivity from 0.0744 to 0.0261 μA/ppm. Similarly, the sensitivities of the Pd/Nafion{\textregistered} and the PPy-modified Pd/Nafion{\textregistered} electrodes decrease by 84 and 68%, respectively, accompanying with the sacrifice of loss in sensitivity from 0.0519 to 0.0262 μA/ppm.",

keywords = "Aging, Chemical vapor deposition, Metallized Nafion{\textregistered} electrodes, Polypyrrole modification",

author = "Liu, {Yu Chuan} and Hwang, {Bing Joe} and Hsu, {Wen Cheng}",

year = "2002",

month = dec,

day = "10",

doi = "10.1016/S0925-4005(02)00250-2",

language = "English",

volume = "87",

pages = "304--308",

journal = "Sensors and Actuators, B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Improvement in anti-aging of metallized Nafion® hydrogen sensors modified by chemical vapor deposition of polypyrrole

AU - Liu, Yu Chuan

AU - Hwang, Bing Joe

AU - Hsu, Wen Cheng

PY - 2002/12/10

Y1 - 2002/12/10

N2 - Pt/Nafion® and Pd/Nafion® electrodes were prepared by impregnation-reduction methods in detecting hydrogen. For improving their anti-aging abilities, polypyrrole (PPy) films were chemically deposited onto the metallized electrodes. After continuously aging tests for 48 h, the sensitivities of the Pt/Nafion® and the PPy-modified Pt/Nafion® electrodes decrease by 68 and 32%, respectively, but the accompanying sacrifice is the loss in sensitivity from 0.0744 to 0.0261 μA/ppm. Similarly, the sensitivities of the Pd/Nafion® and the PPy-modified Pd/Nafion® electrodes decrease by 84 and 68%, respectively, accompanying with the sacrifice of loss in sensitivity from 0.0519 to 0.0262 μA/ppm.

AB - Pt/Nafion® and Pd/Nafion® electrodes were prepared by impregnation-reduction methods in detecting hydrogen. For improving their anti-aging abilities, polypyrrole (PPy) films were chemically deposited onto the metallized electrodes. After continuously aging tests for 48 h, the sensitivities of the Pt/Nafion® and the PPy-modified Pt/Nafion® electrodes decrease by 68 and 32%, respectively, but the accompanying sacrifice is the loss in sensitivity from 0.0744 to 0.0261 μA/ppm. Similarly, the sensitivities of the Pd/Nafion® and the PPy-modified Pd/Nafion® electrodes decrease by 84 and 68%, respectively, accompanying with the sacrifice of loss in sensitivity from 0.0519 to 0.0262 μA/ppm.

KW - Aging

KW - Chemical vapor deposition

KW - Metallized Nafion® electrodes

KW - Polypyrrole modification

UR - http://www.scopus.com/inward/record.url?scp=0037058634&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037058634&partnerID=8YFLogxK

U2 - 10.1016/S0925-4005(02)00250-2

DO - 10.1016/S0925-4005(02)00250-2

M3 - Article

AN - SCOPUS:0037058634

VL - 87

SP - 304

EP - 308

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

IS - 2

ER -