Enhancements in conductivity and thermal and conductive stabilities of electropolymerized polypyrrole with caprolactam-modified clay

Yu Chuan Liu, Chenh Jung Tsai

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

In this study, a polypyrrole (PPy)/caprolactam-modified montmorillonite (MMT) clay composite was electropolymerized on a gold substrate. Basically, the nucleation and growth were instantaneous three-dimensional processes before and after nuclei overlapping for both pure PPy and the composite electropolymerizations. However, a distinguishable feature can be observed. The surface morphology of the resulting composite is denser and more compact. The composite demonstrates an extremely high oxidation level and oxidation degree of 0.41 and 0.59 revealed from the analyses of X-ray photoelectron spectroscopy (XPS) and surface-enhanced Raman scattering (SERS), respectively. The thermal stability of PPy is improved, as shown from thermogravimetric analysis (TGA), due to the modification of the incorporated clay. Also, the conductivity of the composite was significantly increased (∼12 times) and aging is depressed compared to that of pure PPy.

Original languageEnglish
Pages (from-to)320-326
Number of pages7
JournalChemistry of Materials
Volume15
Issue number1
DOIs
Publication statusPublished - Jan 14 2003
Externally publishedYes

Fingerprint

Caprolactam
Polypyrroles
Clay
Composite materials
Bentonite
Oxidation
Electropolymerization
Clay minerals
Gold
Surface morphology
Thermogravimetric analysis
Raman scattering
Thermodynamic stability
Nucleation
X ray photoelectron spectroscopy
Aging of materials
clay
polypyrrole
Hot Temperature
Substrates

ASJC Scopus subject areas

  • Materials Science(all)
  • Materials Chemistry

Cite this

Enhancements in conductivity and thermal and conductive stabilities of electropolymerized polypyrrole with caprolactam-modified clay. / Liu, Yu Chuan; Tsai, Chenh Jung.

In: Chemistry of Materials, Vol. 15, No. 1, 14.01.2003, p. 320-326.

Research output: Contribution to journalArticle

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