Effect of TiO2 nanoparticles on the improved performances on electrochemically prepared surface-enhanced raman scattering-active silver substrates

Yu Chuan Liu, Chung Chin Yu, Ting Chu Hsu

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

In this work, we use electrochemical oxidation-reduction cycles (ORC) methods to prepare surface-enhanced Roman scattering (SERS)-active silver substrates modified with TiO2 nanoparticles to improve the corresponding SERS performances. On the basis of the modified substrates, the SERS of Rhodamine 6G (R6G) exhibits a higher intensity by 4-fold of magnitude, as compared with that of R6G adsorbed on a SERS-active Ag substrate without the modification of TiO2 nanoparticles. Moreover, the SERS enhancement capabilities of the modified and the unmodified Ag substrates are seriously destroyed at temperatures higher than 200 and 125°C, respectively. These results indicate that the modification of TiO2 nanoparticles can improve the thermal stability of SERS-active substrates. More interestingly, the SERS intensity of R6G was significantly increased by 9-fold of magnitude, as the temperature of the modified Ag substrate was raised from 25 to 125°C. The aging in SERS intensity is also depressed on this modified Ag substrate due to the contribution of TiO2 nanoparticles to SERS effects.

Original languageEnglish
Pages (from-to)16022-16027
Number of pages6
JournalJournal of Physical Chemistry C
Volume112
Issue number41
DOIs
Publication statusPublished - Oct 16 2008
Externally publishedYes

Fingerprint

Silver
Raman scattering
silver
Scattering
Raman spectra
Nanoparticles
nanoparticles
Substrates
scattering
rhodamine
electrochemical oxidation
Electrochemical oxidation
Thermodynamic stability
thermal stability
Aging of materials
Temperature
cycles
augmentation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Effect of TiO2 nanoparticles on the improved performances on electrochemically prepared surface-enhanced raman scattering-active silver substrates. / Liu, Yu Chuan; Yu, Chung Chin; Hsu, Ting Chu.

In: Journal of Physical Chemistry C, Vol. 112, No. 41, 16.10.2008, p. 16022-16027.

Research output: Contribution to journalArticle

@article{fa7066b576ab47ffbea6900087e74e33,
title = "Effect of TiO2 nanoparticles on the improved performances on electrochemically prepared surface-enhanced raman scattering-active silver substrates",
abstract = "In this work, we use electrochemical oxidation-reduction cycles (ORC) methods to prepare surface-enhanced Roman scattering (SERS)-active silver substrates modified with TiO2 nanoparticles to improve the corresponding SERS performances. On the basis of the modified substrates, the SERS of Rhodamine 6G (R6G) exhibits a higher intensity by 4-fold of magnitude, as compared with that of R6G adsorbed on a SERS-active Ag substrate without the modification of TiO2 nanoparticles. Moreover, the SERS enhancement capabilities of the modified and the unmodified Ag substrates are seriously destroyed at temperatures higher than 200 and 125°C, respectively. These results indicate that the modification of TiO2 nanoparticles can improve the thermal stability of SERS-active substrates. More interestingly, the SERS intensity of R6G was significantly increased by 9-fold of magnitude, as the temperature of the modified Ag substrate was raised from 25 to 125°C. The aging in SERS intensity is also depressed on this modified Ag substrate due to the contribution of TiO2 nanoparticles to SERS effects.",
author = "Liu, {Yu Chuan} and Yu, {Chung Chin} and Hsu, {Ting Chu}",
year = "2008",
month = "10",
day = "16",
doi = "10.1021/jp805997n",
language = "English",
volume = "112",
pages = "16022--16027",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "41",

}

TY - JOUR

T1 - Effect of TiO2 nanoparticles on the improved performances on electrochemically prepared surface-enhanced raman scattering-active silver substrates

AU - Liu, Yu Chuan

AU - Yu, Chung Chin

AU - Hsu, Ting Chu

PY - 2008/10/16

Y1 - 2008/10/16

N2 - In this work, we use electrochemical oxidation-reduction cycles (ORC) methods to prepare surface-enhanced Roman scattering (SERS)-active silver substrates modified with TiO2 nanoparticles to improve the corresponding SERS performances. On the basis of the modified substrates, the SERS of Rhodamine 6G (R6G) exhibits a higher intensity by 4-fold of magnitude, as compared with that of R6G adsorbed on a SERS-active Ag substrate without the modification of TiO2 nanoparticles. Moreover, the SERS enhancement capabilities of the modified and the unmodified Ag substrates are seriously destroyed at temperatures higher than 200 and 125°C, respectively. These results indicate that the modification of TiO2 nanoparticles can improve the thermal stability of SERS-active substrates. More interestingly, the SERS intensity of R6G was significantly increased by 9-fold of magnitude, as the temperature of the modified Ag substrate was raised from 25 to 125°C. The aging in SERS intensity is also depressed on this modified Ag substrate due to the contribution of TiO2 nanoparticles to SERS effects.

AB - In this work, we use electrochemical oxidation-reduction cycles (ORC) methods to prepare surface-enhanced Roman scattering (SERS)-active silver substrates modified with TiO2 nanoparticles to improve the corresponding SERS performances. On the basis of the modified substrates, the SERS of Rhodamine 6G (R6G) exhibits a higher intensity by 4-fold of magnitude, as compared with that of R6G adsorbed on a SERS-active Ag substrate without the modification of TiO2 nanoparticles. Moreover, the SERS enhancement capabilities of the modified and the unmodified Ag substrates are seriously destroyed at temperatures higher than 200 and 125°C, respectively. These results indicate that the modification of TiO2 nanoparticles can improve the thermal stability of SERS-active substrates. More interestingly, the SERS intensity of R6G was significantly increased by 9-fold of magnitude, as the temperature of the modified Ag substrate was raised from 25 to 125°C. The aging in SERS intensity is also depressed on this modified Ag substrate due to the contribution of TiO2 nanoparticles to SERS effects.

UR - http://www.scopus.com/inward/record.url?scp=55149119189&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=55149119189&partnerID=8YFLogxK

U2 - 10.1021/jp805997n

DO - 10.1021/jp805997n

M3 - Article

AN - SCOPUS:55149119189

VL - 112

SP - 16022

EP - 16027

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 41

ER -