Determination of the second virial coefficient of the interaction between microemulsion droplets by microcalorimetry

Wen Yih Chen, Chih Sheng Kuo, Der Zen Liu

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The study proposes a novel method of obtaining the information of second virial coefficient of interactions between microemulsion droplets by microcalorimetry. By use of a high sensitivity isothermal titration microcalorimetry to measure the dilution heat of microemulsions solution, information about the second virial coefficient of the interactions between the microemulsion droplets can be derived with the number density of microemulsion solution. The derivation is based on a hard-sphere interaction potential assumption. The variance of the derived second virial coefficients was verified by the percolation behavior of different reverse micelles solutions of dioctyl sulfosuccinate sodium salt in decane with or without solutes.

Original languageEnglish
Pages (from-to)300-302
Number of pages3
JournalLangmuir
Volume16
Issue number2
DOIs
Publication statusPublished - Jan 25 2000
Externally publishedYes

Fingerprint

Microemulsions
virial coefficients
heat of solution
Dioctyl Sulfosuccinic Acid
interactions
titration
dilution
micelles
solutes
Micelles
derivation
Titration
sodium
Dilution
salts
Salts
sensitivity
Sodium

ASJC Scopus subject areas

  • Colloid and Surface Chemistry
  • Physical and Theoretical Chemistry

Cite this

Determination of the second virial coefficient of the interaction between microemulsion droplets by microcalorimetry. / Chen, Wen Yih; Kuo, Chih Sheng; Liu, Der Zen.

In: Langmuir, Vol. 16, No. 2, 25.01.2000, p. 300-302.

Research output: Contribution to journalArticle

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