CO2 sequestration by carbonation of steelmaking slags in an autoclave reactor

E. E. Chang, Shu Yuan Pan, Yi Hung Chen, Hsiao Wen Chu, Chu Fang Wang, Pen Chi Chiang

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71 Citations (Scopus)

Abstract

Carbon dioxide (CO2) sequestration experiments using the accelerated carbonation of three types of steelmaking slags, i.e., ultra-fine (UF) slag, fly-ash (FA) slag, and blended hydraulic slag cement (BHC), were performed in an autoclave reactor. The effects of reaction time, liquid-to-solid ratio (L/S), temperature, CO2 pressure, and initial pH on CO2 sequestration were evaluated. Two different CO2 pressures were chosen: the normal condition (700psig) and the supercritical condition (1300psig). The carbonation conversion was determined quantitatively by using thermo-gravimetric analysis (TGA). The major factors that affected the conversion were reaction time (5min to 12h) and temperature (40-160°C). The BHC was found to have the highest carbonation conversion of approximately 68%, corresponding to a capacity of 0.283kgCO2/kgBHC, in 12h at 700psig and 160°C. In addition, the carbonation products were confirmed to be mainly in CaCO3, which was determined by using scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) to analyze samples before and after carbonation. Furthermore, reaction kinetics were expressed with a surface coverage model, and the carbon footprint of the developed technology in this investigation was calculated by a life cycle assessment (LCA).

Original languageEnglish
Pages (from-to)107-114
Number of pages8
JournalJournal of Hazardous Materials
Volume195
DOIs
Publication statusPublished - Nov 15 2011

Keywords

  • Accelerated carbonation
  • Alkaline solid waste
  • Calcite
  • Life cycle assessment
  • Surface coverage model

ASJC Scopus subject areas

  • Health, Toxicology and Mutagenesis
  • Pollution
  • Waste Management and Disposal
  • Environmental Chemistry
  • Environmental Engineering

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    Chang, E. E., Pan, S. Y., Chen, Y. H., Chu, H. W., Wang, C. F., & Chiang, P. C. (2011). CO2 sequestration by carbonation of steelmaking slags in an autoclave reactor. Journal of Hazardous Materials, 195, 107-114. https://doi.org/10.1016/j.jhazmat.2011.08.006