Chemical evidences for the optimal coagulant dosage and pH adjustment of silica removal from chemical mechanical polishing (CMP) wastewater

Wen Hui Kuan, Ching Yao Hu

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The coagulation behavior of aluminum salts in SiO2(s)-containing chemical mechanical polishing (CMP) wastewater was investigated using jar tests and with reference to the coordination chemistry of Al(III) and Si(IV). The results of the jar tests show that the alum dosage did not influence the removal of silica when more than a particular amount of coagulant was added. However, the removal efficiency of the CMP wastewater depended more strongly on pH than on coagulant dosage. Insight into these results was given by the surface complexation model/surface precipitation model (SCM/SPM) and electrophoresis measurements. Simulation results thus obtained demonstrate that the Al(III) released from the coagulant underwent a two-stage reaction in a narrow range of 1.5 pH under under-saturated solution conditions with respect to the Al-hydroxide solid phase. At low pH (3.5-4.3), the Al(III) prevents the natural dissolution of SiO2(s) particles by forming bi-nuclear surface complexes which energetically disfavor the simultaneous removal of two metal centers. In the pH range 4.3-5, the surface precipitation reaction dominated, and both Al(III) and Si(IV) formed a new oxide film in the original surface, protecting against dissolution of SiO2(s) by OH-.

Original languageEnglish
Pages (from-to)1-7
Number of pages7
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume342
Issue number1-3
DOIs
Publication statusPublished - Jun 15 2009

Fingerprint

Coagulants
Chemical mechanical polishing
polishing
Silicon Dioxide
Wastewater
adjusting
Silica
silicon dioxide
dosage
dissolving
Dissolution
alum
coagulation
electrophoresis
Coagulation
Electrophoresis
Complexation
Aluminum
hydroxides
Oxide films

Keywords

  • Chemical mechanical polishing (CMP)
  • Coagulant dosage
  • pH
  • SiO
  • Surface complexation model/surface precipitation model (SCM/SPM)

ASJC Scopus subject areas

  • Colloid and Surface Chemistry

Cite this

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abstract = "The coagulation behavior of aluminum salts in SiO2(s)-containing chemical mechanical polishing (CMP) wastewater was investigated using jar tests and with reference to the coordination chemistry of Al(III) and Si(IV). The results of the jar tests show that the alum dosage did not influence the removal of silica when more than a particular amount of coagulant was added. However, the removal efficiency of the CMP wastewater depended more strongly on pH than on coagulant dosage. Insight into these results was given by the surface complexation model/surface precipitation model (SCM/SPM) and electrophoresis measurements. Simulation results thus obtained demonstrate that the Al(III) released from the coagulant underwent a two-stage reaction in a narrow range of 1.5 pH under under-saturated solution conditions with respect to the Al-hydroxide solid phase. At low pH (3.5-4.3), the Al(III) prevents the natural dissolution of SiO2(s) particles by forming bi-nuclear surface complexes which energetically disfavor the simultaneous removal of two metal centers. In the pH range 4.3-5, the surface precipitation reaction dominated, and both Al(III) and Si(IV) formed a new oxide film in the original surface, protecting against dissolution of SiO2(s) by OH-.",
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AU - Kuan, Wen Hui

AU - Hu, Ching Yao

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N2 - The coagulation behavior of aluminum salts in SiO2(s)-containing chemical mechanical polishing (CMP) wastewater was investigated using jar tests and with reference to the coordination chemistry of Al(III) and Si(IV). The results of the jar tests show that the alum dosage did not influence the removal of silica when more than a particular amount of coagulant was added. However, the removal efficiency of the CMP wastewater depended more strongly on pH than on coagulant dosage. Insight into these results was given by the surface complexation model/surface precipitation model (SCM/SPM) and electrophoresis measurements. Simulation results thus obtained demonstrate that the Al(III) released from the coagulant underwent a two-stage reaction in a narrow range of 1.5 pH under under-saturated solution conditions with respect to the Al-hydroxide solid phase. At low pH (3.5-4.3), the Al(III) prevents the natural dissolution of SiO2(s) particles by forming bi-nuclear surface complexes which energetically disfavor the simultaneous removal of two metal centers. In the pH range 4.3-5, the surface precipitation reaction dominated, and both Al(III) and Si(IV) formed a new oxide film in the original surface, protecting against dissolution of SiO2(s) by OH-.

AB - The coagulation behavior of aluminum salts in SiO2(s)-containing chemical mechanical polishing (CMP) wastewater was investigated using jar tests and with reference to the coordination chemistry of Al(III) and Si(IV). The results of the jar tests show that the alum dosage did not influence the removal of silica when more than a particular amount of coagulant was added. However, the removal efficiency of the CMP wastewater depended more strongly on pH than on coagulant dosage. Insight into these results was given by the surface complexation model/surface precipitation model (SCM/SPM) and electrophoresis measurements. Simulation results thus obtained demonstrate that the Al(III) released from the coagulant underwent a two-stage reaction in a narrow range of 1.5 pH under under-saturated solution conditions with respect to the Al-hydroxide solid phase. At low pH (3.5-4.3), the Al(III) prevents the natural dissolution of SiO2(s) particles by forming bi-nuclear surface complexes which energetically disfavor the simultaneous removal of two metal centers. In the pH range 4.3-5, the surface precipitation reaction dominated, and both Al(III) and Si(IV) formed a new oxide film in the original surface, protecting against dissolution of SiO2(s) by OH-.

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